Yes! Anyone with Staff Permissions is able to skip songs. With that being said, due to licensing agreements, only six songs are allowed to be skipped per hour.
Another option is to Ban songs. Check out this article to learn more about banning music - How do I ban an artist or song?
If you are frequently hitting the skip limit or find that you are banning lots of songs, please contact our support team at support@rockbot.com to help better customize your music library.